FOR TEACHERS ONLY. The University of the State of New York REGENTS HIGH SCHOOL EXAMINATION PHYSICAL SETTING/CHEMISTRY

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FOR TEAERS ONLY P.S. The University of the State of New York REGENTS IG SOOL EXAMINATION PYSIAL SETTING/EMISTRY Wednesday, January 29, 2014 1:15 to 4:15 p.m., only SORING KEY AND RATING GUIDE Directions to the Teacher: Refer to the directions on page 2 before rating student papers. Updated information regarding the rating of this examination may be posted on the New York State Education Department s web site during the rating period. heck this web site at: http://www.p12.nysed.gov/assessment/ and select the link Scoring Information for any recently posted information regarding this examination. This site should be checked before the rating process for this examination begins and several times throughout the Regents Examination period. Part A and Part B 1 Allow 1 credit for each correct response. 1..... 1..... 2..... 3..... 3..... 2..... 4..... 1..... 5..... 3..... 6..... 4..... 7..... 2..... 8..... 3..... 31..... 1..... 32..... 1..... 33..... 4..... 34..... 1..... 35..... 3..... Part A 9..... 1..... 17..... 4..... 10..... 4..... 18..... 3..... 11..... 2..... 19..... 2..... 12..... 3..... 20..... 1..... 13..... 1..... 21..... 2..... 14..... 4..... 22..... 3..... 15..... 4..... 23..... 3..... 16..... 2...... 24..... 2..... Part B 1 36..... 3..... 41..... 3..... 37..... 4..... 42..... 1..... 38..... 2..... 43..... 4..... 39..... 1..... 44..... 4..... 40..... 1..... 45..... 2..... 25..... 1..... 26..... 3..... 27..... 1..... 28..... 4..... 29..... 2..... 30..... 4..... 46..... 2..... 47..... 1..... 48..... 2..... 49..... 3..... 50..... 1.....

Directions to the Teacher Follow the procedures below for scoring student answer papers for the Regents Examination in Physical Setting/hemistry. Additional information about scoring is provided in the publication Information Booklet for Scoring Regents Examinations in the Sciences. Do not attempt to correct the student s work by making insertions or changes of any kind. If the student s responses for the multiple-choice questions are being hand scored prior to being scanned, the scorer must be careful not to make any marks on the answer sheet except to record the scores in the designated score boxes. Marks elsewhere on the answer sheet will interfere with the accuracy of the scanning. Allow 1 credit for each correct response. At least two science teachers must participate in the scoring of the Part B 2 and Part open-ended questions on a student s paper. Each of these teachers should be responsible for scoring a selected number of the open-ended questions on each answer paper. No one teacher is to score more than approximately one-half of the open-ended questions on a student s answer paper. Teachers may not score their own students answer papers. Students responses must be scored strictly according to the Scoring Key and Rating Guide. For openended questions, credit may be allowed for responses other than those given in the rating guide if the response is a scientifically accurate answer to the question and demonstrates adequate knowledge, as indicated by the examples in the rating guide. On the student s separate answer sheet, for each question, record the number of credits earned and the teacher s assigned rater/scorer letter. Fractional credit is not allowed. Only whole-number credit may be given for a response. If the student gives more than one answer to a question, only the first answer should be rated. Units need not be given when the wording of the questions allows such omissions. For hand scoring, raters should enter the scores earned in the appropriate boxes printed on the separate answer sheet. Next, the rater should add these scores and enter the total in the box labeled Total Raw Score. Then the student s raw score should be converted to a scale score by using the conversion chart that will be posted on the Department s web site at: http://www.p12.nysed.gov/assessment/ on Wednesday, January 29, 2014. The student s scale score should be entered in the box labeled Scale Score on the student s answer sheet. The scale score is the student s final examination score. Schools are not permitted to rescore any of the open-ended questions on this exam after each question has been rated once, regardless of the final exam score. Schools are required to ensure that the raw scores have been added correctly and that the resulting scale score has been determined accurately. Because scale scores corresponding to raw scores in the conversion chart may change from one administration to another, it is crucial that, for each administration, the conversion chart provided for that administration be used to determine the student s final score. P.S./hem. Rating Guide Jan. 14 [2]

Part B 2 Allow a total of 15 credits for this part. The student must answer all questions in this part. 51 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Si silicon element 14 52 [1] Allow 1 credit. Acceptable responses include, but are not limited to: As atomic number increases, the electronegativity increases. Electronegativity increases. from lower to higher 53 [1] Allow 1 credit. Acceptable responses include, but are not limited to: White phosphorus has fewer atoms per cm 3. Red has more. Note: Do not allow credit for a response that only indicates the number of atoms per cm 3 in red phosphorus is different from the number of atoms per cm 3 in white phosphorus. 54 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Ga indium element 31 element 49 P.S./hem. Rating Guide Jan. 14 [3]

55 [1] Allow 1 credit. Acceptable responses include, but are not limited to: The entropy of KNO 3 (s) is less than the entropy of KNO 3 (aq). The KNO 3 (aq) is more disordered. The solution is more random than the solid. Note: Do not allow credit for a response that only indicates the entropies are different. 56 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Both samples are at 20., but the larger sample has more matter. The larger sample has twice as many particles. The total thermal energy is directly proportional to the masses of the samples. 57 [1] Allow 1 credit. Acceptable responses include, but are not limited to: The boiling point of the NaNO 3 solution is higher than the boiling point of water. lower for 2 O 58 [1] Allow 1 credit for 30 g/mol, 30. g/mol, or for any value from 30.06 g/mol to 30.1 g/mol, inclusive. 59 [1] Allow 1 credit for 4 or four. 60 [1] Allow 1 credit. Acceptable responses include, but are not limited to: The catalyzed reaction pathway has a lower activation energy than the original reaction. Less energy is needed. 61 [1] Allow 1 credit. Acceptable responses include, but are not limited to: ydrogen atoms are added to the ethene molecule at the site of the carbon-carbon double bond to form a single molecule. Two reactants combine to form a single product. Two substances form one. Two hydrogen atoms are added at. An unsaturated reactant becomes a saturated product. The reaction is a hydrogenation reaction, which is a type of addition reaction. P.S./hem. Rating Guide Jan. 14 [4]

62 [1] Allow 1 credit. Acceptable responses include, but are not limited to: (0.026 M)(50.0 ml) M B (38.5 ml) (. 0 026)( 50) 38. 5 63 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Kl lk K (aq) l (aq) K l 64 [1] Allow 1 credit. Acceptable responses include, but are not limited to: O O alcohol hydroxyl hydroxy group Note: Do not allow credit for hydroxide ion or hydroxyl radical or O. 65 [1] Allow 1 credit. Acceptable responses include, but are not limited to: The number of each kind of atom is the same in both, but their structures are not the same. Their molecular formulas are the same, but their structural arrangement of atoms is different. same molecular formula but different structural formulas The only difference is the arrangement of the atoms. P.S./hem. Rating Guide Jan. 14 [5]

Part Allow a total of 20 credits for this part. The student must answer all questions in this part. 66 [1] Allow 1 credit. Acceptable responses include, but are not limited to: sodium hydrogen carbonate sodium bicarbonate sodium acid carbonate monosodium carbonate bicarbonate of soda 67 [1] Allow 1 credit for 14% or for any value from 14.28% to 14.3%, inclusive. 68 [1] Allow 1 credit for blue. 69 [1] Allow 1 credit for any value from 61 g to 63 g, inclusive. 70 [1] Allow 1 credit for 2 N 4 l ao 2 N 3 2 O al 2. Note: Allow credit even if the coefficient 1 is written in front of ao, 2 O, and/or al 2. 71 [1] Allow 1 credit. Acceptable responses include, but are not limited to: There is a greater electronegativity difference in a O bond than in a bond. The O bond is more polar because the electronegativity difference for a O bond is 0.8, and the electronegativity difference for a bond is 0.4. The bond has a smaller difference. The O is.8 and the is.4. P.S./hem. Rating Guide Jan. 14 [6]

72 [1] Allow 1 credit. Acceptable responses include, but are not limited to: hydrogen bonding dipole dipole 73 [1] Allow 1 credit for any value from 48 kpa to 52 kpa, inclusive. 74 [1] Allow 1 credit. Acceptable responses include, but are not limited to: A 2-propanol molecule is polar because it has an asymmetrical distribution of charge. The charge distribution is uneven. The center of positive charge and the center of negative charge do not coincide. 75 [1] Allow 1 credit. Examples of 1-credit responses: O O O O 76 [1] Allow 1 credit. The position of electrons may vary. Examples of 1-credit responses: S X X S S P.S./hem. Rating Guide Jan. 14 [7]

77 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Ar argon element 18 78 [1] Allow 1 credit. Acceptable responses include, but are not limited to: The rate of the forward reaction is equal to the rate of the reverse reaction. They are the same. equal 79 [1] Allow 1 credit. Acceptable responses include, but are not limited to: 0 to 1 0 to 1 zero to negative one 0 to minus one 80 [1] Allow 1 credit. Acceptable responses include, but are not limited to: The container must be closed so that no matter can enter or leave, thus disturbing the equilibrium. If the container is open, l 2 gas escapes. to keep the concentrations of the reactants and products constant 81 [1] Allow 1 credit. Acceptable responses include, but are not limited to: The concentration of the lo ion decreases. [lo ] decreases. lower lo concentration less lo P.S./hem. Rating Guide Jan. 14 [8]

82 [1] Allow 1 credit for 74. 83 [1] Allow 1 credit. Acceptable responses include, but are not limited to: I-127 atoms and I-131 atoms have the same number of protons, but different numbers of neutrons. Both have 53 p, but I-127 has 74 n while I-131 has 78 n. They have the same atomic number but different mass numbers. same atomic number but different numbers of neutrons The only difference is the number of neutrons. 84 [1] Allow 1 credit. Acceptable responses include, but are not limited to: 104 51 Sb 104 Sb Sb-104 antimony-104 85 [1] Allow 1 credit for 48 d, 48.0 d, 48.1 d, or for any value from 48.12 d to 48.13 d, inclusive. P.S./hem. Rating Guide Jan. 14 [9]

Regents Examination in Physical Setting/hemistry January 2014 hart for onverting Total Test Raw Scores to Final Examination Scores (Scale Scores) The hart for Determining the Final Examination Score for the January 2014 Regents Examination in Physical Setting/hemistry will be posted on the Department s web site at: http://www.p12.nysed.gov/assessment/ on Wednesday, January 29, 2014. onversion charts provided for previous administrations of the Regents Examination in Physical Setting/hemistry must NOT be used to determine students final scores for this administration. Online Submission of Teacher Evaluations of the Test to the Department Suggestions and feedback from teachers provide an important contribution to the test development process. The Department provides an online evaluation form for State assessments. It contains spaces for teachers to respond to several specific questions and to make suggestions. Instructions for completing the evaluation form are as follows: 1. Go to http://www.forms2.nysed.gov/emsc/osa/exameval/reexameval.cfm. 2. Select the test title. 3. omplete the required demographic fields. 4. omplete each evaluation question and provide comments in the space provided. 5. lick the SUBMIT button at the bottom of the page to submit the completed form. P.S./hem. Rating Guide Jan. 14 [10]

Map to ore urriculum January 2014 Physical Setting/hemistry Question Numbers Key Ideas/Performance Indicators Part A Part B Part Standard 1 Math Key Idea 1 62 69, 73 Math Key Idea 2 59 69, 70, 71, 73 Math Key Idea 3 44, 45, 51, 58 67, 71, 79, 84, 85 Science Inquiry Key Idea 1 35, 40, 53, 55, 56, 57, 59, 60, 64, 65 Science Inquiry Key Idea 2 Science Inquiry Key Idea 3 33, 34, 37, 39, 40, 47, 50, 51, 52, 54, 61, 63 Engineering Design Key Idea 1 Standard 2 Key Idea 1 Key Idea 2 Standard 6 Key Idea 1 36 Key Idea 2 38, 65 Key Idea 3 Key Idea 4 80, 81 Key Idea 5 40 Standard 7 Key Idea 1 Key Idea 2 Standard 4 Process Skills Key Idea 3 31, 32, 35, 38, 39, 42, 43, 44, 46, 51, 52, 54, 58, 62, 63, 64 Key Idea 4 34, 40, 41, 45, 48, 49, 56 72, 74, 75, 78, 80, 83 66, 68, 70, 74, 77, 79, 82 68, 69, 70, 75, 78, 81, 82, 83 84, 85 Key Idea 5 76, 77 Standard 4 Key Idea 3 1, 2, 3, 4, 5, 6, 10, 11, 12, 13, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29 31, 32, 37, 38, 39, 42, 43, 44, 46, 47, 48, 51, 52, 54, 55, 57, 58, 60, 61, 62, 63, 64, 65 Key Idea 4 14, 30 36, 40, 45, 49, 56 84, 85 Key Idea 5 7, 8, 9 33, 34, 35, 41, 50, 53, 59 Reference Tables 2011 Edition 1, 2, 3, 5, 6, 11, 16, 21, 22, 23, 24, 26, 28, 29 31, 35, 38, 42, 43, 45, 48, 50, 51, 52, 53, 54, 57, 58, 59, 62, 63, 64 66, 67, 68, 69, 70, 75, 78, 79, 80, 81, 82, 83 71, 72, 73, 74, 76, 77 66, 67, 68, 69, 71, 73, 75, 76, 77, 82, 83, 84, 85 P.S./hem. Rating Guide Jan. 14 [11]