Chemistry 141. Professor James F Harrison. 1:30-2:30 pm MWF Room 37 Chemistry Basement. Office Hours

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Chemistry 141 Professor James F Harrison harrison@chemistry.msu.edu Office Hours 1:30-2:30 pm MWF Room 37 Chemistry Basement

CEM 141 Grade Summary - FALL 2013 GRADE # of Students % of Students 4.0 446 22.1% 3.5 299 14.8% 3.0 314 15.5% 2.5 273 13.5% 2.0 202 10.0% 1.5 170 8.42% 1.0 116 5.74% 75.9% of the students in the fall earned a grade of 2.0 or higher! 0.0 (with final) 140 6.93% 0.0 (no final) 57 2.82%

Course Structure Lectures MWF 3:00 3:50 pm room 138 RecitaOon once a week Room and Ome depends on your secoon If you are in this lecture you are in a secoon between 29 and 42

RecitaOons Weekly Staffed by a Teaching Assistant (TA) Opportunity to ask quesoons and discuss the lecture material Will start Tuesday, September 2 You will receive credit for problem sets a_empted in recitaoon There will be 13 sets but only 10 will be counted and each of those will be worth 5 points Maximum 50 points

Help Room Help with the material covered in CEM 141 is available in the Help Room (Room 83 in the basement) Staffed by TA s

Free tutoring is available at the Learning Resource Center in Bessey Hall and in several residence halls on campus Mock exams LRC.msu.edu

Useful InformaOon General Chemistry Office General informaoon and assistance Room 185 M- F 8-12 noon and 1-5 pm Telephone 5-9715 ext 323 General Chemistry Coordinator Mrs. Wendy Whibord Undergraduate Program Manager Dr. Steve Poulios

Physical Resources Textbook Lecture Notes Old ExaminaOons

Textbook Volume 1 of Chemistry by Hunter & Pollock Chemistry 141 Lecture Notes By P. Hunter

Previous Examinations A book of examinations given previously in CEM 141 is available for $20 from the General Chemistry Office (room 185 Chemistry) or from bookstores in town. The book contains all of the exams, and solutions to the exams, given in the last five years. This is the best purchase you can make

Electronic Resources Web Site Cemscores OWL @

CEM 141 web site h_p://www.chemistry.msu.edu Go to Courses ( upper right) then General Chemistry Courses then CEM 141

cemscores You will be able to view your points for the various exams, homework and recitaoon work More on this later

Homework assignments will be administered by OWL @ system You must purchase an OWL access code

CEM 141 Sections 01-56 Fall 2014 We ll be using OWL (Online Web Learning) as our online homework system this semester. You will need to use OWL in order to get credit for your homework. Here are your directions to get access: 1. Purchase your OWL access code. There are several ways to get the access code: a) Purchased separately or bundled with the Atwood Survival Guide for General Chemistry from local bookstores b) Purchased from CengageBrain website: 24-month access for $50: http://www.cengagebrain.com/micro/1-1pltzjb 6-month access for $42: http://www.cengagebrain.com/micro/1-1plu45f! 2. Open a web browser on your computer and go to www.cengage.com/owl 3. Choose General Chemistry It is recommended that and choose Register you do NOT click here to purchase an access code. It is cheaper and quicker to purchase one as described in step #1 above. 4. Choose: Chemistry &Chemical Reactivity, 8th Edition; Kotz, Treichel, Townsend ISBN 0-840-04828-9 (5 th book from the top) Note that this is not the same text that is used to accompany lecture! 5. Choose: Michigan State University - East Lansing, Michigan 6. Click on the blue arrow under Student Registration 7. Choose the blue arrow next to Chemistry 141 Fall 2014. Enter your information into the Self-Registration form. Your Student Number is your MSU PID. Enter your PID as the letter A followed by 8 digits (no spaces). Type your access code into the Access Code space and press Continue.! Once you reach the Student Registration: Successful Registration page, click on the Login Page link at the top. Bookmark this login page and use it whenever you visit OWL. Use the Login and Password you created during registering.

Homework assignments will be administered by OWL @ system OWL homework opens on Wednesday at 8:00am and is due 10 days la_er on a Saturday at 8:00am First OWL homework opened this morning and is due by 8:00am Saturday September 6

Homework (OWL) Eleven homework assignments will be issued this term There are no make up or extensions offered for missed problem sets. You are encouraged to work together But you are responsible for compleong your own set by Saturday morning at 8:00 am Due dates are listed on the course calendar You have an unlimited number of try s on each quesoon You may earn 160 points or 16% of the total points available

Examinations Three one hour exams Monday evenings 6:45-7:45 pm If for some reason you cannot take the evening exam you may take an alternate exam at 6:45 am on the same day as the evening exam There will not be any makeup exams

Final Exam There will be a 2 hour final examinaoon scheduled from 7:45 9:45 am on Tuesday December 9 If you miss the final exam you will receive a zero for the course

Absence from an exam due to illness must be substantiated by a physician. Absence due to extenuating circumstances must be preapproved. If you miss one hourly exam you will receive a grade for that exam equal to the arithmetic average of the two remaining hourly exams or the final, whichever is lowest. If you miss more than one hourly exam you will receive a grade of zero for that exam.

Points 3 hourly exams (180 each) 540 1 final exam 250 11 problem sets (OWL) 160 10 recitation problems 50 Total points 1000

Grades 1000-800 4.0 799-740 3.5 739-680 3.0 679-620 2.5 619-560 2.0 559-500 1.5 499-440 1.0 439-0 0.0 Scale is fixed and will not be curved

ExaminaOon Schedule exam date :me 1 September 22 6:45-7:45 pm 2 October 20 6:45-7:45 pm 3 November 17 6:45-7:45 pm final December 9 7:45-9:45 am

General Chemistry Awards Three awards will be given to the top three students in CEM141 First award $500 Second award $300 Third award $200

Most of the power point slides from my lectures will be available at www2.chemistry.msu.edu/courses/cem141jo The best way to contact me is by email and the best address is harrison@chemistry.msu.edu Please use cem141 in the subject line

CEM 161 will not meet unol Tuesday September 2

Lecture Notes 1 Units of measurements, calculaoons When we report a measurement we report Number Unit

Units of Measurements ReporOng the measurement of a quanoty without giving its unit is meaningless For example saying that the length of a race is 3 means nothing without the associated unit, say km or miles There are many different units for the same property Length could be angstroms, cenometers, meters, inches, feet, miles, light years, etc

SI units mass kilogram length meter kg m Ome second s temperature Kelvin K amount mole mol current ampere A

EssenOally all science and engineering use the System InternaOonal or SI system Base SI Units Quan:ty unit symbol Mass kilogram kg Length meter m Time second s Temperature degree K Amount mole mol Current ampere A

Common derived units: velocity = length / time = m s 1 acceleration = velocity / time = ms 2 force = mass x acceleration = kg m s 2 = Newton N Energy = Force x distance = Nm = kg m 2 s -2 = Joule J pressure = force / area = N / m 2 = kg m -1 s -2 = Pascal = Pa frequency = 1/ time = s -1 = Hertz = Hz

Oqen powers of 10 are represented by a prefix prefix pico (p) micro (μ) milli (m) Value 10-12 10-6 10-3 kilo (k) 10 3 mega (M) 10 6

7.0 picometers 7.0pm 7.0 x 10-12 m 8.6 micrometers 8.6μm 8.6 x 10-6 m 12.6 kilometers 12.6km 12.6 x 10 3 m

Significant figures How many significant figures are in a number? 1. If there is a decimal point in the number, draw an arrow from leq to right unol you come to the first non- zero digit. All digits you did not draw through are significant. 7532.03 0.004830 6 significant figures 4 significant figures

2. If there is no decimal point in the number draw an arrow from right to leq unol you come to the first nonzero digit. All digits you did not draw through are significant. However this is the minimum number of significant figures in the number. You cant tell about the zeros unless the number is wri_en in scienofic notaoon. 97300 At least 3 significant figures Perhaps 5

ScienOfic NotaOon Represent numbers as a number between 1.000 and 9.999 muloplied by a power of 10. 63.51 0.0271 = 6.351 x 10 = 2.71 x 10-2 7.23 = 7.23 10068 = 1.0068 x 10 4

Return to 97300 9.7300 x 10 4 5 significant figures 9.730 x 10 4 4 significant figures 9.73 x 10 4 3 significant figures