CHEM 3305 SYLLABUS, V. 2. Name Dr. Shervin Fatehi. Telephone (956) Office Science 3.308

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1 Dr. Shervin Fatehi CHEM 3305 SYLLABUS, V. 2 1 PHYSICAL CHEMISTRY II SPRING Course Basics Title Physical Chemistry II Numbers CHEM 3305 (CRN 54657) Credit 3 hours (Note: Lab is a separate 1-hour course, CHEM 3105.) Semester Spring 2017 Room Science Times MW 4:30 5:45 PM 2 Instructor Name Dr. Shervin Fatehi shervin.fatehi@utrgv.edu Telephone (956) Office Science Office Hours M 1 2 PM, T AM, W 6 7 PM (or by appointment) Friendly Office Hour F AM in EEDUC Course Materials Textbook Title Physical Chemistry: Thermodynamics, Structure, and Change Authors Dr. Peter Atkins (Oxford University) Dr. Julio de Paula (Lewis & Clark College) Edition 10th edition Publisher W. H. Freeman and Company Year 2014

2 Dr. Shervin Fatehi CHEM 3305 SYLLABUS, V Required Materials Blackboard. Various course materials will be posted on the Blackboard site, which you can access by logging into with your UTRGV account. Atkins & De Paula s Physical Chemistry. Hardcopy, e-book, or previous editions are all acceptable, though older versions will likely have some differences in content. All versions are available through a wide variety of retailers, and used copies are often available at bargain prices. Scientific calculator. You may not use any other electronic devices during exams. I may refer to a variety of other textbooks on quantum mechanics, spectroscopy, symmetry, etc., throughout the course of the semester. If I base lectures on them to any meaningful extent, I will provide appropriate excerpts on the course website. 3.3 Optional Materials Because our discussion of symmetry in quantum mechanics will involve a fair bit of geometric thinking, you may wish to purchase a molecular modeling kit. Many different kits are available from Amazon and other retailers, at costs ranging from about $20 $40. I do not recommend the Darling Models Molecular Visions kit it s the one I have, and using it is pretty frustrating. As an alternative to a physical modeling kit, you might consider using software that allows you to build and visualize molecules. There are many options, including smartphone apps, but the one that I m most familiar with is IQmol, which is freely available for Windows, OS X, and Linux from Not only can you build your own molecules or draw on a (small) database of saved structures, but you can also use IQmol to perform small electronic structure calculations using Q-CHEM s corporate servers. It s a nice little package! 4 Course Description and Prerequisite Here and elsewhere in this syllabus, text boxes contain information that s consistent across sections of the course, across UTRGV or the UT system, or even across the entire state of Texas; I ll provide my own comments and additions as necessary. Keeping that in mind, the content of CHEM 3305 can be summarized as follows: The second half of physical chemistry investigates concepts in quantum mechanics, group theory and symmetry and spectroscopy. Studies of chemical kinetics and electrochemistry are also included. Catalog description notwithstanding, this course is unlikely to include any sustained discussion of chemical kinetics or electrochemistry, which are typically covered as part of CHEM We will sharpen our focus on the beautiful edifice of quantum mechanics instead!

3 Dr. Shervin Fatehi CHEM 3305 SYLLABUS, V. 2 3 The only catalog prerequisite for this course is CHEM 3304 (Physical Chemistry I), but the classes are largely disconnected. What s more important is that you feel comfortable with the underlying physics and math content, which you can get in the General Physics sequence (PHYS 1401/1402) and in Calculus (MATH 2413/2414/2415 or their honors equivalents). It s also useful to have had some exposure to differential equations and linear algebra, like you might get in MATH 2321 or the corresponding upper-level courses. You should be ready and willing to do some math! 5 Learning Objectives for CHEM 3305 At the end of the semester, you should understand the connection between the quantities we measure in spectroscopic experiments and the structure of atoms and molecules. In particular, you ll understand how atomic and molecular structure is determined by the electrostatic interactions between electrons and nuclei, according to the laws of quantum mechanics. What s more, you ll see how the symmetry of a molecule (or lack thereof) can provide us with all sorts of information about its orbital structure, spectrum, and reactivity. And you ll see why classical physics isn t up to the task of describing chemical systems, thanks to our examination of inexplicable phenomena like the photoelectric effect and spin. 6 Ways to Succeed in CHEM Cultivate Good Habits This is an upper-level course, so much of the responsibility for your performance in the class rests on your shoulders: Read the chapter before lecture; come to class consistently; ask questions (and interrupt me if you have to); take notes, review them, and maybe recopy them; keep up with the material; and do your problem sets! 6.2 Get Help from... Me. It s my job to help you learn physical chemistry, but it s also a lot of fun. Come to my office hours to be announced soon or me to set up an appointment. Each other. Your classmates are a great source of support. One of the best ways to help each other is to form study groups: Make plans to talk about the book and the lectures, work on problem sets, or even come to office hours together! The Learning Center. Free chemistry tutoring is available through the Learning Center. Information is available at Student Accessibility Services. If you have a documented disability of any kind that might affect your performance in the class, let me know as soon as possible and contact Student Accessibility Services (see Section 9.2).

4 Dr. Shervin Fatehi CHEM 3305 SYLLABUS, V Assignments and Grading 7.1 Problem Sets Our discussions of quantum mechanics will be elaborated on in problem sets consisting of questions drawn from Atkins and possibly from other textbooks. These problems are intended to help you learn how to apply the concepts and techniques covered in class, without penalizing you too much for making mistakes. To that end, they will be graded on a completion basis, meaning that numerical answers will be provided to guide you (where applicable) and that a significant amount of work toward answering each of a problem s parts will earn you full credit. I encourage you to work together to figure out the problem sets, but anything you submit must be your own work, in your own handwriting, with your own explanations. Problem sets will be due at the start of class on the date specified when the assignment is handed down. 7.2 Midterm Exams There will be three midterm exams, each covering several chapters of material. Midterms will consist of a mix of multiple-choice and short-answer questions. Challenging questions with several related parts may also appear; as a rule, it will be possible to earn partial credit on multi-part questions and within each of their parts. Midterms will be held on dates to be specified in the Course Calendar, during our scheduled class period and in the usual classroom from 4:30 5:45 PM in Science If you must miss a midterm for an excused absence see Section 9.3 for acceptable excuses you may take it by appointment in my office, typically the day before or after the scheduled date. Keep in mind, however, that any discussion of the exam material with your classmates will constitute a breach of scholastic integrity (see Section 10.2). Unexcused absences from midterms will, of course, result in a grade of zero. The good news is that your lowest-scoring midterm will be dropped and will not factor into your final grade. Even so, missing two midterms will make it impossible to earn better than a low C in the class; if you miss all three exams, you will fail. 7.3 Final Exam Everything we talk about this semester may reappear on the final exam, though it will emphasize the last chapters we cover more than earlier ones. As to be noted in the Course Calendar, the final will be held on Monday, May 8 th, from 5:45 7:30 PM in our usual classroom (Science 1.288). There will be no make-up final do not miss it.

5 Dr. Shervin Fatehi CHEM 3305 SYLLABUS, V Extra Credit You may earn up to 5 points of extra credit on your course grade. These points can be earned in two ways: From time to time this semester, there may be research presentations or other events relevant to our course or to the field of chemistry as a whole. If I designate such an event as eligible for extra credit, you can earn 1 point by attending (as evidenced on a sign-in sheet) and by submitting a 150+ word mini-essay summarizing what you learned on the next school day. I want you to make a habit of coming to office hours, because it has both direct and indirect benefits office hours give you the opportunity to ask specific questions and to become more engaged with me and with the class material. To that end, you can earn 1 point of extra credit each week for coming to an office-hours session and asking me some substantive questions. You can t just come to office hours and sit silently! 7.5 Final Grades Problem sets, two of the midterms, the final, and extra-credit points will all contribute to your grade; your lowest-scoring midterm will be dropped. To obtain your point total for the semester, I will add your scores from each type of assignment and rescale them according to the following scheme: Assignment Type Points Achievable Problem Sets 15 2 Best Midterms 55 Final 30 Extra Credit 5 Entire Course 105 UTRGV grades are letters A, B, C, D, or F, with no +/ modifiers. In this course, your grade will be determined based on a 105-point scale: Points Earned Grade A B C D <60 F Because you will be graded based on fixed grade ranges, nobody is in direct competition with anybody else; if everybody earns 90+ points, everybody will receive an A! That being the case, it s in your interest to help each other learn as much as possible. In the event that the final class average dips below 65%, I will institute a curve that helps everybody at least a little bit. After any curve is applied, grades within a fixed number of points from the boundary between A/B, B/C, and so on may be bumped up to the higher grade (but never down) at my discretion.

6 Dr. Shervin Fatehi CHEM 3305 SYLLABUS, V Course Calendar 8.1 Course Outline A rough outline of the semester is as follows: Weeks 1 2: Foundations and math review. Week 2 3: Chapter 7, Introduction to quantum theory. Weeks 4 5: Chapter 8, The quantum theory of motion. Weeks 6 7: Chapter 9, Atomic structure and spectra. Weeks 8 and 10: Chapter 10, Molecular structure. Week 9: Spring Break! Weeks 11 12: Chapter 11, Molecular symmetry. Weeks 13 14: Chapter 12, Rotational and vibrational spectra. Week 15: Chapter 13, Electronic transitions. Week 16: Chapter 14, Magnetic resonance. Given the flexibility of our schedule, the Course Calendar will be posted on the Blackboard website and updated continuously. Even so, there are a few fixed holidays, deadlines, and special times of the semester that you should be aware of, which I ve listed below. If you re really curious, you can find a complete Academic Calendar covering now until Summer 2017 at it s linked under Resources, under the login pane. M 16 Jan. Martin Luther King, Jr. Holiday and Day of Service. T 17 Jan. Spring classes begin. M 30 Jan. Registration Deadline: Last day to add or register for Spring classes. W 01 Feb. Census Day: Last day to drop a class before it appears on the transcript and counts toward the 6-drop limit. Also the last day to receive a 100% refund for dropped classes (other policies apply if a student withdraws). M 13 F 17 Mar. Spring Break: No class. W 12 Apr. W 03 May. Online course evaluations available. R 13 Apr. Drop/Withdrawal Deadline: Last day for students to drop the course and receive a DR grade (or to withdraw and receive a W). After this date, students will be assigned a letter grade that counts toward the GPA.

7 Dr. Shervin Fatehi CHEM 3305 SYLLABUS, V. 2 7 F 14 Apr. Easter Holiday: No class. R 04 May. Study Day: No class. F 05 R 11 May. Final Exams. F 12/Sa 13 May. Commencement. Wednesday, February 1 st the day before Lecture #5 is also known as Census Day. Your attendance in class through Census Day is important, as described in the policies on Attendance and Course Drops in Sections 9.3 and 9.4. Also, as already noted, our final exam will be held Monday, May 8 th, from 5:45 7:30 PM in our usual classroom (Science 1.288). There will be no make-up final do not miss it. 9 Course Policies 9.1 General Etiquette Stay focused. Questions you ask in class should be questions about chemistry. You can ask other questions about the course, about grading policies, about your grades, etc. during office hours or in a private appointment. Electronic devices. Turn off or silence your phones and pagers when you come to class. You may use a laptop or tablet to take lecture notes, but not to check , surf the web, or otherwise distract yourself. Electronic devices may not be used as a calculator on exam days attempts to use them during exams, for any purpose, may constitute scholastic dishonesty (see Section 10.2). . Whenever you write to me, you should use your UTRGV account. To increase your chances of a fast reply, especially early in the semester before we ve had a chance to get to know each other, I encourage you to read and follow the advice given by Dr. Laura Portwood-Stacer at Students with Disabilities If you have a documented disability (physical, psychological, learning, or other disability which affects your academic performance) and would like to receive academic accommodations, please inform your instructor and contact Student Accessibility Services to schedule an appointment to initiate services. It is recommended that you schedule an appointment with Student Accessibility Services before classes start. However, accommodations can be

8 Dr. Shervin Fatehi CHEM 3305 SYLLABUS, V. 2 8 provided at any time. Brownsville Campus: Student Accessibility Services is located in Cortez Hall Room 129 and can be contacted by phone at (956) (Voice) or via at ability@utrgv.edu. Edinburg Campus: Student Accessibility Services is located in 108 University Center and can be contacted by phone at (956) (Voice), (956) (Fax), or via at ability@utrgv.edu. More information about Student Accessibility Services is available from their website, Attendance Students are expected to attend all scheduled classes and may be dropped from the course for excessive absences. UTRGV s attendance policy excuses students from attending class if they are participating in officially sponsored university activities, such as athletics; for observance of religious holy days; or for military service. Students should contact the instructor in advance of the excused absence and arrange to make up missed work or examinations. I will take attendance from the start of class until Census Day up until Lecture #5; after that, I ll keep track of your participation in the class based on whether you hand in problem sets and take the midterms. For this course, there are two forms of excessive absence that could lead to your being dropped from the course (see Section 9.4): three unexcused absences from lecture before Census Day, or more than one unexcused absence from a midterm exam. You may be excused from class by notifying me at least a week in advance of your participation in UTRGV activities, religious observances, or military service. I will also excuse you for major medical emergencies or the death of a family member; in these cases, you must provide me with a doctor s note or other documentation when you return to campus. 9.4 Course Drops According to UTRGV policy, students may drop any class without penalty, earning a grade of DR, until the official drop date. Following that date, students must be assigned a letter grade and can no longer drop the class. Students considering dropping the class should be aware of the 6-drop and 3-peat rules: The 6-drop rule refers to Texas law dictating that undergraduate students may not drop more than six courses during their undergraduate career. (Courses dropped at other Texas public higher-education institutions will count toward the 6-course drop limit.) The 3-peat rule refers to additional fees charged to students who take the same class for the third time.

9 Dr. Shervin Fatehi CHEM 3305 SYLLABUS, V. 2 9 Students may be dropped from this course for excessive absences or for violations of scholastic integrity (see Section 10.2). 9.5 Mandatory Course Evaluation Period Students are required to complete an ONLINE evaluation of this course, accessed through your UTRGV account ( you will be contacted through with further instructions. Students who complete their evaluations will have priority access to their grades. Online evaluations will be available: Feb 15 Feb 21 for Module 1 courses Apr 12 Apr 18 for Module 2 courses Apr 12 May 3 for full spring semester courses 10 Policies on Safety and Integrity 10.1 Sexual Harassment, Discrimination, and Violence In accordance with UT System regulations, your instructor is a responsible employee for reporting purposes under Title IX regulations and so must report any instance, occurring during a student s time in college, of sexual assault, stalking, dating violence, domestic violence, or sexual harassment about which she/he becomes aware during this course through writing, discussion, or personal disclosure. More information can be found at including confidential resources available on campus. The faculty and staff of UTRGV actively strive to provide a learning, working, and living environment that promotes personal integrity, civility, and mutual respect in an environment free from sexual misconduct and discrimination. Be assured that I will report any instance of harassment, discrimination, or violence that comes to my attention. I want each and every one of you to feel safe in my classroom and at this university! To that same end, I am available to each of you as a participant in the UTRGV ALLY program, which has the goal of providing a SafeZone & support to gay, lesbian, bisexual, transgender, and questioning persons at UTRGV & the Rio Grande Valley community Scholastic Integrity As members of a community dedicated to Honesty, Integrity, and Respect, students are reminded that those who engage in scholastic dishonesty are subject to disciplinary penalties, including the possibility of failure in the course and expulsion from the University. Scholastic dishonesty includes but is not limited to: cheating, plagiarism, and collusion;

10 Dr. Shervin Fatehi CHEM 3305 SYLLABUS, V submission for credit of any work or materials that are attributable in whole or in part to another person; taking an examination for another person; any act designed to give unfair advantage to a student; or the attempt to commit such acts. Since scholastic dishonesty harms the individual, all students, and the integrity of the University, policies on scholastic dishonesty will be strictly enforced (Board of Regents Rules and Regulations and UTRGV Academic Integrity Guidelines). All scholastic dishonesty incidents will be reported to the Dean of Students. As the policy makes clear, scholastic dishonesty can take a variety of forms. The easiest way to avoid committing any of them is to remember that midterms and the final must be entirely your own work, and that electronic devices cannot be used during exams. If I suspect successful cheating on any assignment or if I catch attempted cheating as it happens I will investigate and initiate appropriate disciplinary action. Keep in mind that past instances of dishonesty may be on record, and repeat offenses may lead to more severe penalties!

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